Department of Biological and Chemical Engineering

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 Department of Biological and Chemical Engineering Research Key areas in research & development Process & Materials Engineering Research Groups Intelligent Advanced Materials Publications

Publications

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Provino, A., Smetana, V., Shtender, V., Siebeneichler, S., Putti, M., Franz, A., Ferdeghini, C., Pecharsky, V. K., Mudring, A. V. & Manfrinetti, P. (2024). Unusual superconductivity in crystallographically disordered RT2−xSn2 compounds. Journal of Alloys and Compounds, 1000, Article 175025. https://doi.org/10.1016/j.jallcom.2024.175025
Ponou, S., Miller, G. J. & Mudring, A. V. (2021). Uncovering new transition metal Zintl phases by cation substitution: the crystal chemistry of Ca3CuGe3and Ca2+nMnxAg2−x+zGe2+n−z(n= 3, 4). CrystEngComm, 23(14), 2711-2722. https://doi.org/10.1039/d1ce00094b
Wineinger, H., Smetana, V., Hiti, E., Baryshnikov, G., Qu, F., Ågren, H., Mudring, A. V. & Rogers, R. D. (2023). Trapping an Unexpected/Unprecedented Hexanuclear Ce(III) Hydrolysis Product with Neutral 4-Amino-1,2,4-triazole. European Journal of Inorganic Chemistry, 26(31), Article e202300450. https://doi.org/10.1002/ejic.202300450
Celania, C., Smetana, V., Meyer, G. H. & Mudring, A. V. (2023). The Prolific Ternary System Pt/Sn/Nd: Insertion of Pt into the Structures of Sn/Nd Intermetallics Yields Structural Complexity and Wealth. Inorganic Chemistry, 62(24), 9369-9378. https://doi.org/10.1021/acs.inorgchem.3c00318
Wilk-Kozubek, M., Mudryk, Y., Prodius, D., Dolotko, O., Ahmed, S. J., Overgaard, J., Smetana, V. & Mudring, A. V. (2025). The power of lanthanides: same composition, but different lanthanides leading to different interesting materials properties, from magnetocalorics to molecular magnets and phosphors. Polyhedron, 282, Article 117798. https://doi.org/10.1016/j.poly.2025.117798
Alammar, T., Smetana, V., Pei, H., Hamm, I., Wark, M. & Mudring, A. V. (2021). The Power of Ionic Liquids: Crystal Facet Engineering of SrTiO3 Nanoparticles for Tailored Photocatalytic Applications. Advanced Sustainable Systems, 5(2), Article 2000180. https://doi.org/10.1002/adsu.202000180
Wang, G., Dorn, K. V., Siebeneichler, S., Valldor, M., Smetana, V. & Mudring, A. V. (2022). The missing link between zeolites and polyoxometalates. Science Advances, 8(46), Article eadd9320. https://doi.org/10.1126/sciadv.add9320, https://doi.org/10.1126/sciadv.add9320
Tyvanchuk, Y., Babizhetskyy, V., Baran, S., Szytuła, A., Smetana, V., Lee, S., Oliynyk, A. O. & Mudring, A. V. (2024). The crystal and electronic structure of RE23Co6.7In20.3 (RE = Gd–Tm, Lu): A new structure type based on intergrowth of AlB2- and CsCl-type related slabs. Journal of Alloys and Compounds, 976, Article 173241. https://doi.org/10.1016/j.jallcom.2023.173241
Adranno, B., Renier, O., Bousrez, G., Paterlini, V., Baryshnikov, G. V., Smetana, V., Tang, S., Ågren, H., Metlen, A., Edman, L., Mudring, A.-V. & Rogers, R. D. (2023). The 8-Hydroxyquinolinium Cation as a Lead Structure for Efficient Color-Tunable Ionic Small Molecule Emitting Materials. Advanced Photonics Research. https://doi.org/10.1002/adpr.202200279
Babizhetskyy, V., Myakush, O., Kotur, B., Zheng, C., Smetana, V. & Mudring, A. V. (2024). Ternary gallide Zr7Pd7–xGa3+x (0 ≤ x ≤ 1.8): Synthesis, crystal and electronic structures. Journal of Solid State Chemistry, 340, Article 125034. https://doi.org/10.1016/j.jssc.2024.125034
Babizetskyy, V., Myakush, O., Zelinskiy, A., Kotur, B., Zheng, C., Smetana, V. & Mudring, A. V. (2025). Ternary Gallide Hf7Pd7Ga3: Crystal and Electronic Structures. Zeitschrift fur Anorganische und Allgemeine Chemie, 651(5), Article e202400204. https://doi.org/10.1002/zaac.202400204
Leu, M., Campbell, P. & Mudring, A. V. (2021). Synthesis of luminescent semiconductor nanoparticles in ionic liquids –the importance of the ionic liquid in the formation of quantum dots. Green Chemistry Letters and Reviews, 14(1), 127-135. https://doi.org/10.1080/17518253.2021.1875057
Alammar, T. & Mudring, A. V. (2024). Synthesis and Exploration of Barium Stannate-Zirconate BaSn1-xZrxO3 (0 ≤ X ≤ 1) Solid Solutions as Photocatalysts. Inorganic Chemistry, 63(14), 6132-6140. https://doi.org/10.1021/acs.inorgchem.3c02874
Pakhira, S., Lee, Y., Ke, L., Smetana, V., Mudring, A.-V., Heitmann, T., Vaknin, D. & Johnston, D. C. (2021). Suppression of antiferromagnetic order and strong ferromagnetic spin fluctuations in Ca(Co1−xNix)2−yAs2 single crystals. Physical Review B, 104(9), Article 094420. https://doi.org/10.1103/PhysRevB.104.094420
Kelley, S. P., Smetana, V., Mudring, A. V. & Rogers, R. D. (2021). Structural analysis of mono-substituted N-butyl-pyridinium salts: in search of ionic liquids. Journal of Coordination Chemistry, 74(1-3), 117-128. https://doi.org/10.1080/00958972.2021.1876851
Provino, A., Pecharsky, V. K., Bernini, C., Smetana, V., Mudring, A. V. & Manfrinetti, P. (2023). Solubility limits, magnetic and magnetocaloric properties of MoB-type GdCoxNi1−x (0.47 ≤ x ≤ 0.72). Journal of Alloys and Compounds, 948, Article 169605. https://doi.org/10.1016/j.jallcom.2023.169605
Hammond, O., Morris, D., Bousrez, G., Li, S., de Campo, L., Recsei, C., Moir, M., Glavatskih, S., Rutland, M. & Mudring, A.-V. (2024). Small-Angle Neutron Scattering Insights into 2-Ethylhexyl Laurate: A Remarkable Bioester. ACS Sustainable Chemistry & Engineering, 12(5), 1816-1821. https://doi.org/10.1021/acssuschemeng.3c04736
Pakhira, S., Sangeetha, N. S., Smetana, V., Mudring, A. V. & Johnston, D. C. (2021). Short-range ferromagnetic order due to Ir substitutions in single-crystalline Ba(Co1-xIrx)2As2 (0 ≤ x ≤ 0.25). Journal of Physics Condensed Matter, 33(11), Article 115802. https://doi.org/10.1088/1361-648X/abd339
Renier, O., Bousrez, G., Baryshnikov, G. V., Paterlini, V., Smetana, V., Ågren, H., Rogers, R. D. & Mudring, A. V. (2021). Shape Preserving Single Crystal to Amorphous to Single Crystal Polymorphic Transformation Is Possible. Journal of the American Chemical Society, 143(48), 20202-20206. https://doi.org/10.1021/jacs.1c08590
Smetana, V., Kelley, S. P., Pei, H., Mudring, A. V. & Rogers, R. D. (2021). Sandwiched Kagomé Lattices in a Coordination Polymer Based on Mixed-Valent Uranium. Crystal Growth and Design, 21(3), 1727-1733. https://doi.org/10.1021/acs.cgd.0c01626
Bousrez, G., Renier, O., Kelley, S. P., Adranno, B., Tahavori, E., Titi, H. M., Smetana, V., Tang, S.-F., Mudring, A.-V. & Rogers, R. D. (2021). Ready Access to Anhydrous Anionic Lanthanide Acetates by Using Imidazolium Acetate Ionic Liquids as the Reaction Medium. Chemistry - A European Journal, 27(52), 13181-13189. https://doi.org/10.1002/chem.202100141
Bousrez, G., Hammond, O. S., Renier, O., Boudier, A., Li, S., Whitten, A. E., de Campo, L., Glavatskih, S., Rutland, M. W. & Mudring, A. V. (2025). Phosphonium Bis(oxalato)borate Dicationic Ionic Liquids: A Platform for Halogen-Free Functional Fluids. ACS Sustainable Chemistry and Engineering, 13(48), 20728-20736. https://doi.org/10.1021/acssuschemeng.5c08209
Shi, R. & Mudring, A.-V. (2022). Phonon-Mediated Nonradiative Relaxation in Ln3+-Doped Luminescent Nanocrystals. ACS Materials Letters, 4(10), 1882–1903. https://doi.org/10.1021/acsmaterialslett.2c00595
Ovchinnikov, A. & Mudring, A.-V. (2021). Overlooked Binary Compounds Uncovered in the Reinspection of the La–Au System: Synthesis, Crystal Structures, and Electronic Properties of La7Au3, La3Au2, and La3Au4. Inorganic Chemistry, 60(16), 12158-12171. https://doi.org/10.1021/acs.inorgchem.1c01355
Ponou, S., Lidin, S. & Mudring, A. V. (2023). Optimization of Chemical Bonding through Defect Formation and Ordering-The Case of Mg7Pt4Ge4. Inorganic Chemistry, 62(22), 8519-8529. https://doi.org/10.1021/acs.inorgchem.2c04312
Babizhetskyy, V., Köhler, J., Myakush, O., Smetana, V., Levytskyi, V. & Mudring, A. V. (2021). New intermetallics R1+xZr1−xNi (R = Er–Tm, x ~ 0.5) with the TiNiSi type of structure. Intermetallics: including metallic glasses, 137, Article 107279. https://doi.org/10.1016/j.intermet.2021.107279
Prokop, K. A., Guzik, M., Guyot, Y., Boulon, G., Wilk-Kozubek, M., Sobczyk, M., Mudring, A. V. & Cybińska, J. (2022). Nano-crystalline Nd3+-doped LuPO4 optical materials obtained by ionic liquid assisted synthesis route. Materials Science and Engineering B: Advanced Functional Solid-State Materials, 275, Article 115503. https://doi.org/10.1016/j.mseb.2021.115503
Hammond, O. S., Bousrez, G., Mehler, F., Li, S., Shimpi, M. R., Doutch, J., Cavalcanti, L., Glavatskih, S., Antzutkin, O. N., Rutland, M. W. & Mudring, A. V. (2023). Molecular Architecture Effects on Bulk Nanostructure in Bis(Orthoborate) Ionic Liquids. Small, 19(43), Article 2300912. https://doi.org/10.1002/smll.202300912
Tyvanchuk, Y., Lee, S., Babizhetskyy, V., Smetana, V., Mudring, A. V., Dzevenko, M., Jaffal, E. I., Selvaratnam, B. & Oliynyk, A. O. (2025). Materials Informatics Tools to Analyze Crystal Structures: Crystal Structure of the Novel Ternary Indide ErCo2In. Integrating Materials and Manufacturing Innovation, 14(2), 170-187. Article 101017. https://doi.org/10.1007/s40192-025-00400-x
Shi, R., Lin, L., Wang, Z., Zou, Q. & Mudring, A. V. (2024). Manipulation of Luminescence via Surface Site Occupation in Ln3+-Doped Nanocrystals. Journal of the American Chemical Society, 146(17), 11924-11931. https://doi.org/10.1021/jacs.4c00052
Siebeneichler, S., Ovchinnikov, A., Sheptyakov, D. & Mudring, A. V. (2024). Making a Hedgehog Spin-Vortex State Possible: Geometric Frustration on a Square Lattice. Chemistry of Materials, 36(8), 3546-3554. https://doi.org/10.1021/acs.chemmater.3c02170
Ritter, C., Provino, A., Pecharsky, V. K., Lamura, G., Fauth, F., Smetana, V., Mudring, A. V. & Manfrinetti, P. (2024). Magnetic structures and properties of new 1:1 MoB-type RCo0.6Ni0.4 and RCo0.5Ni0.5 (R = Tb, Dy, Ho): Structural transition induced by magnetic ordering. Journal of Alloys and Compounds, 972, Article 172690. https://doi.org/10.1016/j.jallcom.2023.172690
Bousrez, G., Renier, O., Paterlini, V., Smetana, V. & Mudring, A. V. (2021). Magnetic, Photo- And Electroluminescent: Multifunctional Ionic Tb Complexes. Inorganic Chemistry, 60(23), 17487-17497. https://doi.org/10.1021/acs.inorgchem.1c01875
Siebeneichler, S., Ovchinnikov, A., Bosch-Santos, B., Cabrera-Pasca, G. A., Flacau, R., Huang, Q., Carbonari, A. W., Ryan, D. & Mudring, A. V. (2022). Magnetic phase diagram of the solid solution LaMn2(Ge1−xSix)2 (0 ≤ x ≤ 1) unraveled by powder neutron diffraction. Scientific Reports, 12(1), Article 9248. https://doi.org/10.1038/s41598-022-12549-y
Monteiro, B., Leal, J. P., Mendes, R. F., Almeida Paz, F. A., Linden, A., Smetana, V., Mudring, A. V., Avó, J. & Pereira, C. C. L. (2022). Lanthanide-based complexes as efficient physiological temperature sensors. Materials Chemistry and Physics, 277, Article 125424. https://doi.org/10.1016/j.matchemphys.2021.125424
Smetana, V., Grilli, D., Shtender, V., Pani, M., Manfrinetti, P. & Mudring, A. V. (2024). La-Ni-Si: A Gold Mine with a Diamond. Inorganic Chemistry, 63(48), 22761-22770. https://doi.org/10.1021/acs.inorgchem.4c03560
Hiti, E. A., Mishra, M. K., Smetana, V., Mudring, A. V. & Rogers, R. D. (2023). Isolation of anhydrous tetrabutylphosphonium lanthanide hexa- and penta-nitrates from ionic liquids. Polyhedron, 232, Article 116277. https://doi.org/10.1016/j.poly.2022.116277
Hammond, O. S. & Mudring, A.-V. (2022). Ionic liquids and deep eutectics as a transformative platform for the synthesis of nanomaterials. Chemical Communications, 58(24), 3865-3892. https://doi.org/10.1039/d1cc06543b
Bousrez, G., Renier, O., Adranno, B., Smetana, V. & Mudring, A. V. (2021). Ionic Liquid-Based Dye-Sensitized Solar Cells—Insights into Electrolyte and Redox Mediator Design. ACS Sustainable Chemistry and Engineering, 9(24), 8107-8114. https://doi.org/10.1021/acssuschemeng.1c01057
Renier, O., Bousrez, G., Smetana, V., Mudring, A. V. & Rogers, R. D. (2023). Investigation of the role of hydrogen bonding in ionic liquid-like salts with both N- and S-soft donors. CrystEngComm, 25(4), 530-540. https://doi.org/10.1039/d2ce00961g
Babizhetskyy, V., Lomnytska, Y., Dzevenko, M., Zheng, C., Smetana, V. & Mudring, A. V. (2021). Investigation in the ternary Ta-Ni-P system: Solid state phase equilibria at T=1070 K, crystal and electronic structures of new ternary phosphides. Journal of Alloys and Compounds, 864, Article 158122. https://doi.org/10.1016/j.jallcom.2020.158122
Shtender, V., Smetana, V., Crivello, J. C., Kravets, A., Gondek, Ł., Mudring, A. V. & Sahlberg, M. (2024). Intermetallics of 4:4:1 and 3:3:1 series in La–(Co,Ni)–M (M = Bi, Pb, Te, Sb, Sn and Ga, Al) systems and their properties. Journal of Alloys and Compounds, 982, Article 173767. https://doi.org/10.1016/j.jallcom.2024.173767
Siebeneichler, S., Dorn, K. V., Ovchinnikov, A., Papawassiliou, W., da Silva, I., Smetana, V., Pell, A. J. & Mudring, A.-V. (2022). Frustration and 120° Magnetic Ordering in the Layered Triangular Antiferromagnets AFe(PO3F)2 (A = K, (NH4)2Cl, NH4, Rb, and Cs). Chemistry of Materials, 34(17), 7982-7994. https://doi.org/10.1021/acs.chemmater.2c01916
Siebeneichler, S., Dorn, K., Smetana, V., Ovchinnikov, A. & Mudring, A.-V. (2022). From a Dense Structure to Open Frameworks: The Structural Plethora of Alkali Metal Iron Fluorophosphates. Inorganic Chemistry, 61(25), 9767–9775. https://doi.org/10.1021/acs.inorgchem.2c01205
Pani, M., Provino, A., Smetana, V., Shtender, V., Bernini, C., Mudring, A. V. & Manfrinetti, P. (2022). Four ternary silicides in the La-Ni-Si system: from polyanionic layers to frameworks. CrystEngComm, 24(47), 8219-8228. https://doi.org/10.1039/d2ce01007k
Ovchinnikov, A. & Mudring, A. V. (2022). Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8. Inorganic Chemistry, 61(25), 9756-9766. https://doi.org/10.1021/acs.inorgchem.2c01248
Tang, S., Liu, Y., Opoku, H., Gregorsson, M., Zhang, P., Auroux, E., Dang, D., Mudring, A. V., Wågberg, T., Edman, L. & Wang, J. (2023). Fluorescent carbon dots from birch leaves for sustainable electroluminescent devices. Green Chemistry, 25(23), 9884-9895. https://doi.org/10.1039/d3gc03827k
Pakhira, S., Lee, Y., Kundu, A. K., Islam, F., Ning, Z., Smetana, V., Mudring, A. V., Heitmann, T., Vescovo, E., Ke, L., Vaknin, D. & Johnston, D. C. (2025). Flat-band tuning and emergent itinerant magnetism in Sr(Co1−xPdx)2As2. Proceedings of the National Academy of Sciences of the United States of America, 122(51), Article e2519523122. https://doi.org/10.1073/pnas.2519523122
Sangeetha, N. S., Pakhira, S., Ding, Q. P., Krause, L., Lee, H. C., Smetana, V., Mudring, A. V., Iversen, B. B., Furukawa, Y. & Johnston, D. C. (2021). First-order antiferromagnetic transitions of SrMn2P2 and CaMn2P2 single crystals containing corrugated-honeycomb Mn sublattices. Proceedings of the National Academy of Sciences (PNAS), 118(44), Article e2108724118. https://doi.org/10.1073/pnas.2108724118
Hiti, E. A., Wineinger, H., Smetana, V., Mudring, A. V. & Rogers, R. D. (2024). Exploring the Role of Neutral 4-Amino-1,2,4-triazole in the Formation of Hexanuclear f-Element Hydrolysis Products. Crystal Growth and Design, 24(2), 834-842. https://doi.org/10.1021/acs.cgd.3c01318

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Revised 13.11.2025
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Lara O'Dwyer Brown